Defect-induced magnetism in SiC probed by nuclear magnetic resonance

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Z. T. Zhang - , Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • D. Dmytriieva - , Helmholtz-Zentrum Dresden-Rossendorf, TUD Dresden University of Technology (Author)
  • S. Molatta - , Chair of Solid State Physics/Electronic Properties, Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • J. Wosnitza - , Chair of Physics of High Magnetic Fields, Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • Yutian Wang - , Helmholtz-Zentrum Dresden-Rossendorf, Xidian University (Author)
  • M. Helm - , Chair of Semiconductor Spectroscopy, Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • Shengqiang Zhou - , Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • H. Kühne - , Helmholtz-Zentrum Dresden-Rossendorf (Author)

Abstract

We give evidence for intrinsic defect-induced bulk paramagnetism in SiC by means of C13 and Si29 nuclear magnetic resonance (NMR) spectroscopy. The temperature dependence of the internal dipole-field distribution, probed by the spin part of the NMR Knight shift and the spectral linewidth, follows the Curie law and scales very well with the macroscopic dc susceptibility. In order to quantitatively analyze the NMR spectra, a microscopic model based on dipole-dipole interactions was developed. The very good agreement between these simulations and the NMR data establishes a direct relation between the frequency distribution of the spectral intensity and the corresponding real-space volumes of nuclear spins. The presented approach by NMR can be applied to a variety of similar materials and, thus, opens a new avenue for the microscopic exploration and exploitation of diluted bulk magnetism in semiconductors.

Details

Original languageEnglish
Article number085203
JournalPhysical Review B
Volume95
Issue number8
Publication statusPublished - 8 Feb 2017
Peer-reviewedYes