Crystal-field splitting and correlation effect on the electronic structure of A2IrO3
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Contributors
Abstract
The electronic structure of the honeycomb lattice iridates Na 2IrO3 and Li2IrO3 has been investigated using resonant inelastic x-ray scattering (RIXS). Crystal-field-split d-d excitations are resolved in the high-resolution RIXS spectra. In particular, the splitting due to noncubic crystal fields, derived from the splitting of jeff=3/2 states, is much smaller than the typical spin-orbit energy scale in iridates, validating the applicability of jeff physics in A2IrO3. We also find excitonic enhancement of the particle-hole excitation gap around 0.4 eV, indicating that the nearest-neighbor Coulomb interaction could be large. These findings suggest that both Na2IrO3 and Li2IrO3 can be described as spin-orbit Mott insulators, similar to the square lattice iridate Sr2IrO4.
Details
Original language | English |
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Article number | 076402 |
Journal | Physical review letters |
Volume | 110 |
Issue number | 7 |
Publication status | Published - 13 Feb 2013 |
Peer-reviewed | Yes |