Crystal-field splitting and correlation effect on the electronic structure of A2IrO3

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • H. Gretarsson - , University of Toronto (Author)
  • J. P. Clancy - , University of Toronto (Author)
  • X. Liu - , Brookhaven National Laboratory (Author)
  • J. P. Hill - , Brookhaven National Laboratory (Author)
  • Emil Bozin - , Brookhaven National Laboratory (Author)
  • Yogesh Singh - , Indian Institute of Science Education and Research Mohali (Author)
  • S. Manni - , University of Göttingen (Author)
  • P. Gegenwart - , University of Göttingen (Author)
  • Jungho Kim - , Argonne National Laboratory (Author)
  • A. H. Said - , Argonne National Laboratory (Author)
  • D. Casa - , Argonne National Laboratory (Author)
  • T. Gog - , Argonne National Laboratory (Author)
  • M. H. Upton - , Argonne National Laboratory (Author)
  • Heung Sik Kim - , Seoul National University (Author)
  • J. Yu - , Seoul National University (Author)
  • Vamshi M. Katukuri - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • L. Hozoi - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Jeroen Van Den Brink - , Chair of Solid State Theory, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Young June Kim - , University of Toronto (Author)

Abstract

The electronic structure of the honeycomb lattice iridates Na 2IrO3 and Li2IrO3 has been investigated using resonant inelastic x-ray scattering (RIXS). Crystal-field-split d-d excitations are resolved in the high-resolution RIXS spectra. In particular, the splitting due to noncubic crystal fields, derived from the splitting of jeff=3/2 states, is much smaller than the typical spin-orbit energy scale in iridates, validating the applicability of jeff physics in A2IrO3. We also find excitonic enhancement of the particle-hole excitation gap around 0.4 eV, indicating that the nearest-neighbor Coulomb interaction could be large. These findings suggest that both Na2IrO3 and Li2IrO3 can be described as spin-orbit Mott insulators, similar to the square lattice iridate Sr2IrO4.

Details

Original languageEnglish
Article number076402
JournalPhysical review letters
Volume110
Issue number7
Publication statusPublished - 13 Feb 2013
Peer-reviewedYes

Keywords

ASJC Scopus subject areas