Coupled coherent states method for tunneling dynamics: an interpretative study

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Abstract

Numerical solutions of the time-dependent Schrödinger equation based on the variational principle may offer physical insight that cannot be gained by a solution using fixed grids in position and momentum space. Here we focus on the tunneling dynamics in a quartic double-well and the use of classical, trajectory-guided coherent states to gain insight into the workings of the coupled coherent states method developed by Shalashilin and Child [J. Chem. Phys. 113, 10028 (2000)]. It is shown that over-the-barrier classical trajectories, alone, can accurately describe the tunneling effect.

Details

Original languageEnglish
Article number012005
JournalJournal of Physics: Conference Series
Volume2883
Issue number1
Publication statusPublished - 2024
Peer-reviewedYes

Conference

Title19th International Symposium on Symmetries in Science Symposia
Abbreviated titleSIS XIX
Conference number19
Duration30 July - 4 August 2023
LocationGasthof Hotel Lamm
CityBregenz
CountryAustria

Keywords

ASJC Scopus subject areas