Controlling and Optimizing Amplified Spontaneous Emission in Perovskites

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Perovskites are currently attracting extensive research interest as a wavelength-Tunable lasing material. As a first step toward electrically pumped lasers, numerous investigations have recently reported amplified spontaneous emission (ASE) of optically pumped perovskites with remarkably low thresholds. Here, we investigate the optical aspects of perovskite ASE, to establish the design principle of materials and devices. We show that compared to solution-processed CsPbBr3, vacuum deposition yields superior ASE characteristics with a threshold of 35 μJ/cm2. The optical loss (Rloss) during lateral photon propagation in the waveguide mode is identified as a key parameter to determine the ASE quality. With spatially resolved photoluminescence, we determine Rloss as 40 and >1000 cm-1 for vacuum and solution-processed perovskites, respectively. We present a comprehensive model that relates ASE, gain length, optical loss, temperature, and density of states. Finally, we succeed in demonstrating ASE in perovskite samples with metal electrodes, mimicking a diode architecture for electrical pumping. Optical spacer layers are shown to play a crucial role in preventing metal absorption loss in waveguide modes.

Details

Original languageEnglish
Pages (from-to)35242-35249
Number of pages8
JournalACS applied materials & interfaces
Volume12
Issue number31
Publication statusPublished - 5 Aug 2020
Peer-reviewedYes

External IDs

PubMed 32658443
Scopus 85089709515

Keywords

Keywords

  • CsPbBr3perovskite, amplified spontaneous emission, perovskite laser, population inversion, spatially resolved photoluminescence, vacuum-processed perovskite