Contribution to the crystal chemistry of rare earth chalcogenides: I. The compounds with layer structures LnX2

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • P. Bottcher - , TUD Dresden University of Technology (Author)
  • Th Doert - , Chair of Inorganic Chemistry II (Author)
  • H. Arnold - , RWTH Aachen University (Author)
  • R. Tamazyan - , RWTH Aachen University (Author)

Abstract

A number of lanthanide compounds LnX2 (Ln=Sc, Y, La-Lu; X=S, Se, Te), LnY2 (Y=P, As, Sb), and LnZ2 (Z = Si, Ge) are known to crystallize with a structure derivable from only one aristotype, the ZrSSi type. This structure type contains square layers of silicon atoms (in general: square layers of the element of medium electronegativity). The structural deviations observed within the different compounds are usually small and principally affect this square layer. The space groups of the derivative structures under consideration are subgroups of that of the aristotype and the group-subgroup relations are outlined. Distortions of the square layers caused by electronic reasons can mostly be understood by applying simple electron counting rules. A number of compounds with chalcogen deficiency LnX(2-δ) is noted, too, in which the occurrence of vacancies in the square layers often leads to even larger superstructures.

Details

Original languageEnglish
Pages (from-to)246-253
Number of pages8
JournalZeitschrift fur Kristallographie : international journal for structural, physical, and chemical aspects of crystalline materials
Volume215
Issue number4
Publication statusPublished - 2000
Peer-reviewedYes

External IDs

ORCID /0000-0001-7523-9313/work/142238656
Scopus 85026034775
Scopus 0033803348