Conformations and controlled manipulation of a long molecular wire on Cu(1 1 1)

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Letizia Savio - , Free University of Berlin (Author)
  • Francesca Moresco - , Free University of Berlin (Author)
  • Leo Gross - , Free University of Berlin (Author)
  • André Gourdon - , Center for Materials Elaboration and Structural Studies (Author)
  • Christian Joachim - , Center for Materials Elaboration and Structural Studies (Author)
  • Karl Heinz Rieder - , Free University of Berlin (Author)

Abstract

Low temperature scanning tunnelling microscopy is employed to investigate in detail the conformations of single Violet Lander molecules (C 108H104) on Cu(1 1 1). The molecule consists of a long polyaromatic molecular board supported by four spacer legs. Several conformations, corresponding to different positions of the legs, are observed and characterised, showing that a much larger variety of conformations is possible compared with the other molecules of the Lander family. This is due to the longer central board and the consequently larger distance between the legs. Moreover, tip-induced conformational changes and molecular displacement are achieved in manipulation experiments.

Details

Original languageEnglish
Pages (from-to)38-46
Number of pages9
JournalSurface science
Volume585
Issue number1-2
Publication statusPublished - 1 Jul 2005
Peer-reviewedYes
Externally publishedYes

External IDs

ORCID /0000-0001-9607-8715/work/142252636

Keywords

Research priority areas of TU Dresden

Keywords

  • Lander molecule, Manipulation, Molecular wire, STM