Comparison of Electronic Resistance Measurement Methods and Influencing Parameters for LMFP and High-Nickel NCM Cathodes

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Christoph Seidl - , Chair of Inorganic Non-Metallic Materials, Mercedes-Benz Group AG (Author)
  • Sören Thieme - , Mercedes-Benz Group AG (Author)
  • Martin Frey - , Mercedes-Benz Group AG (Author)
  • Kristian Nikolowski - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Alexander Michaelis - , Chair of Inorganic Non-Metallic Materials, Fraunhofer Institute for Ceramic Technologies and Systems (Author)

Abstract

The automotive industry aims for the highest possible driving range (highest energy density) in combination with a fast charge ability (highest power density) of electric vehicles. With both targets being intrinsically contradictory, it is important to understand and optimize resistances within lithium-ion battery (LIB) electrodes. In this study, the properties and magnitude of electronic resistance contributions in LiMn0.7Fe0.3PO4 (LMFP)- and LiNixCoyMnzO2 (NCM, x = 0.88~0.90, x + y + z = 1)-based electrodes are comprehensively investigated through the use of different measurement methods. Contact resistance properties are characterized via electrochemical impedance spectroscopy (EIS) on the example of LMFP cathodes. The EIS results are compared to a two-point probe as well as to the results obtained using a novel commercial 46-point probe system. The magnitude and ratio of contact resistance and compound electronic resistance for LMFP- and NCM-based cathodes are discussed on the basis of the 46-point probe measurement results. The results show that the 46-point probe yields significantly lower resistance values than those in EIS studies. Further results show that electronic resistance values in cathodes can vary over several orders of magnitude. Various influence parameters such as electrode porosity, type of current collector and the impact of solvent soaking on electronic resistance are investigated.

Details

Original languageEnglish
Article number105
JournalBatteries
Volume10
Issue number3
Publication statusPublished - Mar 2024
Peer-reviewedYes

Keywords

Sustainable Development Goals

Keywords

  • cathode, conductive additives, contact resistance, electrode characterisation methods, electronic limitations, lithium-ion battery