Characterization of the microporosity of different metal-organic frameworks using 129Xe NMR spectroscopy
Research output: Contribution to book/conference proceedings/anthology/report › Chapter in book/anthology/report › Contributed › peer-review
Contributors
Abstract
A series of metal-organic frameworks (MOF) like Zn-MOF-5, TT-1, Cd-, and Co-MOF are investigated using 129Xe NMR spectroscopy. 129Xe NMR experiments are performed over a xenon pressure range from 5 kPa to 150 kPa for studying properties of the MOF's such as the pore dimensions, geometry of the pores, coadsorbed phases, and the influence of the composition of the materials on the chemical shift of the adsorbed xenon. The differences observed in the chemical shifts values can be attributed to different types of micropores generated by the synthesis procedure and the composition of the materials.
Details
| Original language | English |
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| Title of host publication | From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference |
| Publisher | W B SAUNDERS CO-ELSEVIER INC |
| Pages | 2030-2036 |
| Number of pages | 7 |
| Edition | B |
| ISBN (print) | 0444530681, 9780444530684 |
| Publication status | Published - 2007 |
| Peer-reviewed | Yes |
Publication series
| Series | Studies in Surface Science and Catalysis |
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| Number | B |
| Volume | 170 |
| ISSN | 0167-2991 |