Cellulose lattice strains and stress transfer in native and delignified wood
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Small specimens of spruce wood with different degrees of delignification were studied using in-situ tensile tests and simultaneous synchrotron X-ray diffraction to reveal the effect of delignification and densification on their tensile properties at relative humidities of 70–80 %. In addition to mechanical properties, these analyses yield the ratio of strains in the cellulose crystals and in the bulk, which reflects the stress-transfer to crystalline cellulose. While the specific modulus of elasticity slightly increases from native wood by partial or complete delignification, the lattice strain ratio does not show a significant change. This could indicate a compensatory effect from the decomposition of the amorphous matrix by delignification and from a tighter packing of cellulose crystals that would increase the stress transfer. The reduced strain to failure and maximum lattice strain of delignified specimens suggests that the removal of lignin affects the stress-strain behavior with fracture at lower strain levels.
Details
Original language | English |
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Article number | 119922 |
Journal | Carbohydrate polymers |
Volume | 296 |
Publication status | Published - 15 Nov 2022 |
Peer-reviewed | Yes |
External IDs
Scopus | 85135718076 |
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Keywords
Keywords
- Cellulose lattice strain, Delignified wood, In-situ tensile tests, Stress-strain behavior, Stress-transfer