Cellulose Carbonates: A Platform for Promising Biopolymer Derivatives With Multifunctional Capabilities

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Thomas Elschner - , Friedrich Schiller University Jena (Author)
  • Thomas Heinze - , Friedrich Schiller University Jena (Author)

Abstract

Cellulose carbonates as a platform compound open new possibilities for the design of advanced materials based on the most important renewable resource cellulose. In the present feature, the chemistry of cellulose carbonates is discussed considering own research results adequately. After a short overview about methods for activation of polysaccharides for a conversion with nucleophilic compounds in particlur with amines, details about various methods for the synthesis of polysaccharide carbonates are discussed. The main issue of the feature is the synthesis and aminolysis of cellulose carbonates with low, intermediate, and high degree of substitution and the evaluation of this chemistry with respect to specific challenges. Functional cellulose carbamates, obtained from cellulose phenyl carbonate by aminolysis, show the potential use of this class of celluloses. Immunoassays and zwitterionic polymers are included as representative examples regarding properties and application of the new cellulose-based products.

Details

Original languageEnglish
Pages (from-to)735-746
Number of pages12
JournalMacromolecular bioscience
Volume15
Issue number6
Publication statusPublished - Jun 2015
Peer-reviewedYes
Externally publishedYes

External IDs

Scopus 84930664011

Keywords

Sustainable Development Goals

Keywords

  • cellulose, carbonates, functional cellulose carbamates, immunoassays, synthesis, CYANOGEN-BROMIDE, ALKYL CHLOROFORMATES, SURFACE MODIFICATION, REDUCTIVE AMINATION, LITHIUM-CHLORIDE, ORGANIC CYANATES, CLICK CHEMISTRY, DEXTRAN, POLYSACCHARIDES, FLUOROFORMATES