Catanionic bilayers as micro-crystals with in-plane ordered alternated charges

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Th Zemb - , French Alternative Energies and Atomic Energy Commission (CEA) (Author)
  • D. Carrière - , French Alternative Energies and Atomic Energy Commission (CEA) (Author)
  • K. Glinel - , Max Planck Institute of Colloids and Interfaces (Author)
  • M. Hartman - , Max Planck Institute of Colloids and Interfaces (Author)
  • A. Meister - , French Alternative Energies and Atomic Energy Commission (CEA) (Author)
  • Cl Vautrin - , French Alternative Energies and Atomic Energy Commission (CEA) (Author)
  • N. Delorme - , Max Planck Institute of Colloids and Interfaces (Author)
  • A. Fery - , Max Planck Institute of Colloids and Interfaces (Author)
  • M. Dubois - , French Alternative Energies and Atomic Energy Commission (CEA), Max Planck Institute of Colloids and Interfaces (Author)

Abstract

Recent progresses in the understanding of properties of catanionic surfactant aggregates are reviewed. These aggregates are charged micro-crystals produced upon co-crystallisation of anionic and cationic surfactants without excess salt. They were studied applying methods developed for polyelectrolyte multilayered capsules. They have been observed without special preparation by soft X-ray microscopy. Confocal optical microscopy allowed first measurements of the diameter of the holes present at vertices. These observations could be rationalized by identifying the formation path in the phase prism. Rigidity was measured directly using the colloidal probe method and calculated using mesoscopic modelling. These progresses made within of the French-German network are discussed versus recent results obtained by other groups working on catanionics.

Details

Original languageEnglish
Pages (from-to)37-45
Number of pages9
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume303
Issue number1-2
Publication statusPublished - 1 Aug 2007
Peer-reviewedYes
Externally publishedYes

Keywords

Keywords

  • Catanionics, Colloids, Crystallisation, Microscopy, Surfactant mixtures