Carbodiphosphorane mediated synthesis of a triflyloxyphosphonium dication and its reactivity towards nucleophiles
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
A carbodiphosphorane ((Ph 3P) 2C) mediated synthesis of the first triflyloxyphosphonium dication (12+) bearing two electrophilic sites is presented. Depending on the nucleophile, 12+ reacts selectively either at the sulfur atom of the triflyloxy moiety or at the directly attached phosphorus atom. In substitution reactions at the phosphorus atom the triflyloxy moiety serves as a leaving group and enables the synthesis of rare examples of pseudo-halophosphonium dications.
Details
Original language | English |
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Pages (from-to) | 2954-2957 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 53 |
Issue number | 20 |
Publication status | Published - 7 Mar 2017 |
Peer-reviewed | Yes |
External IDs
PubMedCentral | PMC5433424 |
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Scopus | 85014665454 |
ORCID | /0000-0001-7323-7816/work/142257456 |