Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Ariane Brandenburg - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Denis S. Krylov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Alexander Beger - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Anja U.B. Wolter - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Bernd Büchner - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Alexey A. Popov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

Carbide clusterfullerene DyYTiC@C80-Ih with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C80 are compared to those of DySc2N@C80 and the influence of the central atom in the endohedral cluster is analyzed.

Details

Original languageEnglish
Pages (from-to)10683-10686
Number of pages4
JournalChemical communications
Volume54
Issue number76
Publication statusPublished - 2018
Peer-reviewedYes

External IDs

PubMed 30087957

Keywords

ASJC Scopus subject areas