Atomically precise bottom-up fabrication of graphene nanoribbons

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Jinming Cai - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Pascal Ruffieux - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Rached Jaafar - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Marco Bieri - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Thomas Braun - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Stephan Blankenburg - , Swiss Federal Laboratories for Materials Science and Technology (Empa) (Author)
  • Matthias Muoth - , ETH Zurich (Author)
  • Ari P. Seitsonen - , University of Zurich, Pierre and Marie Curie University (Author)
  • Moussa Saleh - , Max Planck Institute for Polymer Research (Author)
  • Xinliang Feng - , Max Planck Institute for Polymer Research (Author)
  • Klaus Müllen - , Max Planck Institute for Polymer Research (Author)
  • Roman Fasel - , Swiss Federal Laboratories for Materials Science and Technology (Empa), University of Bern (Author)

Abstract

Graphene nanoribbons-narrow and straight-edged stripes of graphene, or single-layer graphite-are predicted to exhibit electronic properties that make them attractive for the fabrication of nanoscale electronic devices. In particular, although the two-dimensional parent material graphene exhibits semimetallic behaviour, quantum confinement and edge effects should render all graphene nanoribbons with widths smaller than 10-nm semiconducting. But exploring the potential of graphene nanoribbons is hampered by their limited availability: although they have been made using chemical, sonochemical and lithographic methods as well as through the unzipping of carbon nanotubes, the reliable production of graphene nanoribbons smaller than 10-nm with chemical precision remains a significant challenge. Here we report a simple method for the production of atomically precise graphene nanoribbons of different topologies and widths, which uses surface-assisted coupling of molecular precursors into linear polyphenylenes and their subsequent cyclodehydrogenation. The topology, width and edge periphery of the graphene nanoribbon products are defined by the structure of the precursor monomers, which can be designed to give access to a wide range of different graphene nanoribbons. We expect that our bottom-up approach to the atomically precise fabrication of graphene nanoribbons will finally enable detailed experimental investigations of the properties of this exciting class of materials. It should even provide a route to graphene nanoribbon structures with engineered chemical and electronic properties, including the theoretically predicted intraribbon quantum dots, superlattice structures and magnetic devices based on specific graphene nanoribbon edge states.

Details

Original languageEnglish
Pages (from-to)470-473
Number of pages4
JournalNature
Volume466
Issue number7305
Publication statusPublished - 23 Jul 2010
Peer-reviewedYes
Externally publishedYes

External IDs

PubMed 20651687

Keywords

ASJC Scopus subject areas