Anisotropic Particle-Hole Excitations in Black Phosphorus

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • R. Schuster - , Leibniz Institute for Solid State and Materials Research Dresden (First author)
  • J. Trinckauf - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • C. Habenicht - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • M. Knupfer - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • B. Büchner - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Last author)

Abstract

We report on the energy- and momentum-resolved optical response of black phosphorus (BP) in its bulk form. Along the armchair direction of the puckered layers, we find a highly dispersive mode that is strongly suppressed in the perpendicular (zigzag) direction. This mode emerges out of the single-particle continuum for finite values of momentum and is therefore interpreted as an exciton. We argue that this exciton, which has already been predicted theoretically for phosphorene—the monolayer form of BP—can be detected by conventional optical spectroscopy in the two-dimensional case and might pave the way for optoelectronic applications of this emerging material.

Details

Original languageEnglish
Pages (from-to)026404
Number of pages5
JournalPhysical review letters
Volume115
Publication statusPublished - 10 Jul 2015
Peer-reviewedYes

External IDs

Scopus 84937860333

Keywords