Algorithm to Identify Vapor-Liquid-Liquid Equilibria of Binary Mixtures from Vapor-Liquid Equilibria
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
In this work, we demonstrate that tracing the vapor-liquid equilibria for binary mixtures also includes all the information needed to obtain the three-phase line if one is present. This simple observation serves as a launching point for calculation of the liquid-liquid equilibrium and three-phase equilibria, even when one component is supercritical. We close with the demonstration of the automatic construction of an isothermal pressure-composition figure, a capability enabled by solving for the three-phase state. The scripts in the Supporting Information demonstrate in detail how the method is applied.
Details
Original language | English |
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Pages (from-to) | 2592-2599 |
Number of pages | 8 |
Journal | Industrial and Engineering Chemistry Research |
Volume | 61 |
Issue number | 6 |
Publication status | Published - 16 Feb 2022 |
Peer-reviewed | Yes |
External IDs
ORCID | /0000-0001-7908-4160/work/168204408 |
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