A SEMICLASSICAL CORRELATION-FUNCTION APPROACH TO BARRIER TUNNELING

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Harvard University

Abstract

A time domain approach employing the semiclassical approximation to the quantum mechanical propagator, as applied to Gaussian wavepackets, is used to study the barrier penetration problem. We have observed that qualitative agreement with the exact quantum calculations for the correlation function and the transmission probability can be achieved by considering only classically allowed trajectories. The results slowly tend to the classical step function at the barrier top as a function of the wavepacket center parameter, however. We suggest that a full semiclassical calculation, including nonclassical trajectories with complex energies, would improve the results.

Details

Original languageEnglish
Pages (from-to)45-50
Number of pages6
JournalChemical physics letters
Volume241
Issue number1-2
Publication statusPublished - 14 Jul 1995
Peer-reviewedYes

External IDs

Scopus 0001779097

Keywords

Keywords

  • S-MATRIX THEORY, DYNAMICS