A novel method for the synthesis of alkoxyamine initiators for nitroxide-mediated radical polymerization using Mn(OAc)(3) as electron-transfer reagent
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
O-substituted hydroxylamines which are known to initiate and promote nitroxide-mediated radical polymerization were synthesized in high yield by a novel and facile synthetic approach. Using the favorable Mn(OAc)(3) as electron transfer agent in the in situ generation of benzylic radicals and their trapping by nitroxide radicals provides a new powerful and more economic way to the desired alkoxyamine initiators for this controlled, living radical polymerization. TEMPO, TIPNO and the protected tris-hydroxy derivative of TIPNO were used to synthesize the appropriate alkoxyamines.
Details
Original language | English |
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Pages (from-to) | 391-397 |
Number of pages | 7 |
Journal | Designed monomers and polymers : an international journal on monomer and macromolecular synthesis |
Volume | 7 |
Issue number | 4 |
Publication status | Published - 2004 |
Peer-reviewed | Yes |
Externally published | Yes |
External IDs
Scopus | 4043152110 |
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ORCID | /0000-0002-4531-691X/work/148607680 |
Keywords
Keywords
- Mn(OAc)(3), NMRP initiators, Alkoxyamines, Nitroxide radicals