Stacking Polymorphism in PtSe2 Drastically Affects Its Electromechanical Properties

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Roman Kempt - , Professur für Theoretische Chemie (Autor:in)
  • Sebastian Lukas - , RWTH Aachen University (Autor:in)
  • Oliver Hartwig - , Universität der Bundeswehr München (Autor:in)
  • Maximilian Prechtl - , Universität der Bundeswehr München (Autor:in)
  • Agnieszka Kuc - , Helmholtz-Zentrum Dresden-Rossendorf (Autor:in)
  • Thomas Brumme - , Professur für Theoretische Chemie (Autor:in)
  • Sha Li - , AMO GmbH (Autor:in)
  • Daniel Neumaier - , AMO GmbH, University of Wuppertal (Autor:in)
  • Max C. Lemme - , RWTH Aachen University (Autor:in)
  • Georg S. Duesberg - , Universität der Bundeswehr München (Autor:in)
  • Thomas Heine - , Professur für Theoretische Chemie, Helmholtz-Zentrum Dresden-Rossendorf, Yonsei University (Autor:in)

Abstract

PtSe2 is one of the most promising materials for the next generation of piezoresistive sensors. However, the large-scale synthesis of homogeneous thin films with reproducible electromechanical properties is challenging due to polycrystallinity. It is shown that stacking phases other than the 1T phase become thermodynamically available at elevated temperatures that are common during synthesis. It is shown that these phases can make up a significant fraction in a polycrystalline thin film and discuss methods to characterize them, including their Seebeck coefficients. Lastly, their gauge factors, which vary strongly and heavily impact the performance of a nanoelectromechanical device are estimated.

Details

OriginalspracheEnglisch
Aufsatznummer2201272
FachzeitschriftAdvanced science
Jahrgang9
Ausgabenummer22
PublikationsstatusVeröffentlicht - 5 Aug. 2022
Peer-Review-StatusJa

Externe IDs

PubMed 35652199
Mendeley ed18d9d6-7f30-3662-ae52-87bc605ee98d

Schlagworte

Schlagwörter

  • density-functional theory, piezoresistive sensors, PtSe, Raman characterization, stacking disorder, two-dimensional materials, PtSe2