Glassy dynamics in nanometer thin layers of polystyrene
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Broadband Dielectric Spectroscopy (BDS) and Ellipsometry are combined to study the glassy dynamics of nanometric layers (>= 5 nm) of polystyrene. For the former, two types of sample arrangement are applied, that is, the conventional method where evaporated metal electrodes are used and a novel technique in which insulating silica nanostructures serve as spacers between highly conducting doped silicon counter electrodes. Within the limits of the experimental accuracy (+/- 2K) both approaches, BDS and Ellipsometry, deliver the coinciding result that - compared to the bulk - the glassy dynamics is not shifted. Furthermore the dielectric measurements do not indicate any broadening of the relaxation time distribution function, independent of the sample geometry employed.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 173-180 |
Seitenumfang | 8 |
Fachzeitschrift | European physical journal special topics : ST |
Jahrgang | 189 |
Ausgabenummer | 1 |
Publikationsstatus | Veröffentlicht - Okt. 2010 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |
Externe IDs
Scopus | 78449235349 |
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ORCID | /0000-0002-4531-691X/work/148607819 |
Schlagworte
Schlagwörter
- Ultrathin polymer-films, Transition temperature, Relaxations, Viscosity, Mobility, Oxide