Glassy dynamics in nanometer thin layers of polystyrene

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • E. U. Mapesa - , Universitätsklinikum Leipzig (Autor:in)
  • M. Erber - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • M. Tress - , Universitätsklinikum Leipzig (Autor:in)
  • K. -J. Eichhorn - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • A. Serghei - , University of Massachusetts Amherst (Autor:in)
  • B. Voit - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • F. Kremer - , Universitätsklinikum Leipzig (Autor:in)

Abstract

Broadband Dielectric Spectroscopy (BDS) and Ellipsometry are combined to study the glassy dynamics of nanometric layers (>= 5 nm) of polystyrene. For the former, two types of sample arrangement are applied, that is, the conventional method where evaporated metal electrodes are used and a novel technique in which insulating silica nanostructures serve as spacers between highly conducting doped silicon counter electrodes. Within the limits of the experimental accuracy (+/- 2K) both approaches, BDS and Ellipsometry, deliver the coinciding result that - compared to the bulk - the glassy dynamics is not shifted. Furthermore the dielectric measurements do not indicate any broadening of the relaxation time distribution function, independent of the sample geometry employed.

Details

OriginalspracheEnglisch
Seiten (von - bis)173-180
Seitenumfang8
FachzeitschriftEuropean physical journal special topics : ST
Jahrgang189
Ausgabenummer1
PublikationsstatusVeröffentlicht - Okt. 2010
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

Scopus 78449235349
ORCID /0000-0002-4531-691X/work/148607819

Schlagworte

Schlagwörter

  • Ultrathin polymer-films, Transition temperature, Relaxations, Viscosity, Mobility, Oxide