Poling and structuring of ferroelectric domains form the basis for developing prospective applications using materials from the lithium-niobate (LN) family. Applications range from second harmonic generation to electro-optic modulators or surface acoustic wave devices. In the work presented here, hysteresis measurements are used as a standard method to quantitatively determine the poling properties of these ferroelectrics, including their spontaneous polarization Ps as well as their forward and reverse coercive fields Ec,+ and Ec,−. Systematic measurements that depend on parameters such as the ramp rate R of the applied poling voltage and the waiting time twait between domain inversions are investigated and compared between the congruent variants of LN, lithium tantalate (LT), their magnesium-doped analogues, and stoichiometric LN. For bulk magnesium-doped LN, for example, it is found that the resulting coercive field strongly depends on the speed of the voltage ramp, with EcEc values ranging from 11 to 21 kV mm−1. These investigations are used as fundamental input for poling ferroelectric lithium niobate-tantalate solids (LNT), a system that offers a high potential for tuning the material parameters beyond what is possible for LN or LT.