Electrophoresis of soft particles at high electrolyte concentrations: an interpretation by the Henry theory

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

The existence of electrophoretic mobility at high electrolyte concentrations defines a remarkable peculiarity in the electrosurface characteristics of soft particles. According to Ohshima [H. Ohshima, Colloids Surf. 103 (1995) 249], this effect is caused by the electroosmotic flow within the soft particle shell. An explanation supporting Ohshima's conclusion can be derived from classic electrokinetic theories. Based on the Henry theory [D.C. Henry, Proc. R. Soc. London Ser. A 133 (1931) 106], we demonstrate that the electrophoretic mobility of soft particles does not disappear at decinormal concentration.

Details

OriginalspracheEnglisch
Seiten (von - bis)676-9
Seitenumfang4
FachzeitschriftJournal of colloid and interface science
Jahrgang313
Ausgabenummer2
PublikationsstatusVeröffentlicht - 15 Sept. 2007
Peer-Review-StatusJa

Externe IDs

Scopus 34547197322
ORCID /0000-0003-0189-3448/work/173985697

Schlagworte

Schlagwörter

  • Electrolytes/chemistry, Electroosmosis, Electrophoresis, Models, Chemical