Confinement and Exciton Binding Energy Effects on Hot Carrier Cooling in Lead Halide Perovskite Nanomaterials
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
The relaxation of the above-gap (“hot”) carriers in lead halide perovskites (LHPs) is important for applications in photovoltaics and offers insights into carrier-carrier and carrier-phonon interactions. However, the role of quantum confinement in the hot carrier dynamics of nanosystems is still disputed. Here, we devise a single approach, ultrafast pump-push-probe spectroscopy, to study carrier cooling in six different size-controlled LHP nanomaterials. In cuboidal nanocrystals, we observe only a weak size effect on the cooling dynamics. In contrast, two-dimensional systems show suppression of the hot phonon bottleneck effect common in bulk perovskites. The proposed kinetic model describes the intrinsic and density-dependent cooling times accurately in all studied perovskite systems using only carrier-carrier, carrier-phonon, and excitonic coupling constants. This highlights the impact of exciton formation on carrier cooling and promotes dimensional confinement as a tool for engineering carrier-phonon and carrier-carrier interactions in LHP optoelectronic materials.
Details
Originalsprache | Englisch |
---|---|
Seiten (von - bis) | 6638-6648 |
Seitenumfang | 11 |
Fachzeitschrift | ACS nano |
Jahrgang | 17 |
Ausgabenummer | 7 |
Publikationsstatus | Veröffentlicht - 11 Apr. 2023 |
Peer-Review-Status | Ja |
Externe IDs
PubMed | 36939330 |
---|---|
WOS | 000962222000001 |
Schlagworte
Fächergruppen, Lehr- und Forschungsbereiche, Fachgebiete nach Destatis
Ziele für nachhaltige Entwicklung
ASJC Scopus Sachgebiete
Schlagwörter
- hot carriers, nanocrystals, nanoplatelets, two-dimensional perovskites, ultrafast spectroscopy, Nanoplatelets, Nanocrystals, Two-dimensional perovskites, Hot carriers, Ultrafast spectroscopy