Characterization and modeling cure- and pressure-dependent thermo-mechanical and shrinkage behavior of fast curing epoxy resins

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

A fast crosslinking reaction is crucial for the economical production of automotive components in liquid composite molding (LCM) processes. Although a large number of works have focused on modeling of shrinkage induced surface waviness and part distortions and the underlying phenomena an accurate determination of material properties under consideration of processing parameters still represents a major challenge for fast-curing epoxy resins. Fast-curing epoxy polymers allow manufacturing of thermoset composite parts in minutes while entailing a highly exothermic heat generation. Cure is carried out under elevated temperatures and pressures and is accompanied by a change in density due to chemical shrinkage and followed by thermal contraction. In the present study, comprehensive results on the characterization of thermo-mechanical properties, pressure dependent reaction kinetics and shrinkage are presented for a fast curing epoxy resin. The obtained results give important advice for improved process modeling and facilitate prioritisation for future characterisation of fast-curing epoxy resins.

Details

OriginalspracheEnglisch
Aufsatznummer107498
Seitenumfang9
FachzeitschriftPolymer testing
Jahrgang108
PublikationsstatusVeröffentlicht - Apr. 2022
Peer-Review-StatusJa

Externe IDs

Mendeley 6a38dbb9-ba4b-391f-8fd3-05bd6039b6f7
WOS 000765513200006
ORCID /0000-0002-0169-8602/work/142242247
ORCID /0000-0003-1370-064X/work/142243566
ORCID /0000-0002-0820-8936/work/142245866
ORCID /0000-0003-3624-3242/work/142255825

Schlagworte

Forschungsprofillinien der TU Dresden

DFG-Fachsystematik nach Fachkollegium

Schlagwörter

  • Chemical shrinkage, Fast-curing resin, Reaction kinetics, Thermal expansion