Analysis of two-dimensional energy and relaxation-time distributions from temperature-dependent broadband dielectric spectroscopy
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
We present a method to determine the two-dimensional 2D distribution (Formula presented) of the relaxation time (Formula presented) using an inversion of temperature-dependent broadband dielectric data. In contrast to the usual evaluation of 1D distributions (Formula presented), the 2D analysis reveals whether the broadening of a relaxation peak has its physical origins in a variation of the activation energy (Formula presented), or the preexponential factor (Formula presented) or both. A study of the (Formula presented) relaxation of a polymer blend demonstrates the validity of the analysis. We compare the distribution obtained from dielectric ac data (5 Hz-300 MHz, 100 K-300 K) with the results of a thermally stimulated depolarization currents sampling technique. The contour line of (Formula presented) is shown to follow the compensation law.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 8763-8766 |
Seitenumfang | 4 |
Fachzeitschrift | Physical Review B - Condensed Matter and Materials Physics |
Jahrgang | 57 |
Ausgabenummer | 15 |
Publikationsstatus | Veröffentlicht - 1998 |
Peer-Review-Status | Ja |
Externe IDs
ORCID | /0000-0002-3894-9831/work/142252678 |
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