Unimolecular amplifier: principles of a three-terminal device with power gain

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

A single molecule composed of three linked moieties can function as an amplifier of electrical current, when certain conditions are met by the molecular orbitals of the three component parts. This device should exhibit power gain at appropriate voltages. In this work, we will explain a plausible mechanism by which this device should work, and present its operating characteristics. In particular, we find that a fundamental requirement for current amplification is to have the LUMO of the central moiety more strongly coupled to a control electrode than it is to the other orbitals in the molecule, while the HOMO of this moiety should be more strongly coupled to the orbitals in the other moieties than it is to the control electrode.

Details

OriginalspracheEnglisch
Seiten (von - bis)6975-6984
Seitenumfang10
FachzeitschriftNanoscale
Jahrgang5
Ausgabenummer15
PublikationsstatusVeröffentlicht - 7 Aug. 2013
Peer-Review-StatusJa

Externe IDs

Scopus 85016439092