Tolerance of Flexible MOFs toward Repeated Adsorption Stress
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
The adsorption/desorption cyclability of four flexible MOFs, namely, MIL-53(Al), ELM-11, DUT-8(Ni), and SNU-9, was studied at 298 K using n-butane as adsorptive. The detailed analysis of thermal response curves, physisorption isotherm data, powder X-ray diffraction patterns, as well as SEM images revealed the highly stable switching performance of MIL-53(Al) and ELM-11 materials during 100 adsorption/desorption cycles. In contrast, for DUT-8(Ni) and SNU-9, the multiple adsorption/desorption stress leads to the reduction of crystallite size, causing changes in the switching behavior in the initial 10 physisorption runs, and a characteristic shift of the "gate-opening" pressure to higher values is observed.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 22292-22300 |
Seitenumfang | 9 |
Fachzeitschrift | ACS Applied Materials and Interfaces |
Jahrgang | 7 |
Ausgabenummer | 40 |
Publikationsstatus | Veröffentlicht - 14 Okt. 2015 |
Peer-Review-Status | Ja |
Schlagworte
ASJC Scopus Sachgebiete
Schlagwörter
- adsorption stress, DUT-8(Ni), ELM-11, flexible metal-organic frameworks, InfraSORP, MIL-53(Al), SNU-9