Synthesis of nanocomposites by in situ metallocene-catalyzed polymerization of propene
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Organo-modified aluminophosphate with kanemite-like structure was used for the in situ synthesis of polypropylene (PP) nanocomposites performed by metallocene-catalyzed polymerization. The filler exhibits a layered structure with different organic pending groups arranged in the interlayer space. Melt-compounded composites with the same filler were prepared for comparison.X-ray diffraction (XRD) and transmission electron microscopy (TEM) proved exfoliation of the filler in the PP matrix and formation of nanocomposite after in situ synthesis. In contrast, in the melt-composites the filler is agglomerated and only microcomposites are obtained. (C) 2014 Elseviet Ltd. All rights reserved.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 238-251 |
Seitenumfang | 14 |
Fachzeitschrift | European Polymer Journal |
Jahrgang | 65 |
Publikationsstatus | Veröffentlicht - Apr. 2015 |
Peer-Review-Status | Ja |
Externe IDs
Scopus | 84925399713 |
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ORCID | /0000-0002-4531-691X/work/148607950 |
Schlagworte
Schlagwörter
- Aluminophosphate, Kanemite structure, Metallocene, Nanocomposites, Polyolefins