Synthesis of amphiphilic graft copolymers by ring-opening polymerization of 2-methyl-2-oxazoline initiated by poly[isobutene-co-(p,m-chloromethylstyrene)] macroinitiators

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • O Nuyken - (Autor:in)
  • JR Sanchez - (Autor:in)
  • B. Voit - , Technische Universität München (Autor:in)

Abstract

poly[isobutene-co-(p,m-chloromethylstyrene)]-graft-poly(2-methyl-2-oxazoline) graft copolymers (GP) were prepared by the ''grafting from'' method through the cationic polymerization of 2-methyl-2-oxazoline (MeOXA) initiated by a statistical copolymer is isobutene and chloromethylstyrene. The unusual viscosity behavior in chloroform solution of these polymers, the dynamic laser light scattering analysis in aqueous solution, as well as the solubility in polar solvents Like water and methanol demonstrate the amphiphilic character of the graft copolymers and indicate the formation of aggregates in solution.

Details

OriginalspracheEnglisch
Seiten (von - bis)125-131
Seitenumfang7
FachzeitschriftMacromolecular rapid communications
Jahrgang18
Ausgabenummer2
PublikationsstatusVeröffentlicht - Feb. 1997
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

Scopus 0642362943
ORCID /0000-0002-4531-691X/work/148607625

Schlagworte

Schlagwörter

  • Macromonomers, Mechanism, Kinetics