Two new carboxylate silver(I) complexes, namely [Ag₂(C₄H₆O₄N)]NO₃·H₂O or [Ag₂(HIDA)]NO₃·H₂O with IDA = iminodiacetate (1) and Ag₆(C₆H₆O₆N)₂ or Ag₆(NTA)₂ with NTA = nitrilotriacetate (2) are synthesized and characterized by X-ray powder diffraction, thermal analysis and infrared spectroscopy. Rietveld refinement reveals [Ag₂(HIDA)]NO₃·H₂O to form a 2D coordination polymer while Ag₆(NTA)₂ forms a 3D network, both featuring short Ag(d¹⁰)–Ag(d¹⁰) contacts. The resulting complexes are suitable precursors for the printing of silver structures at low temperature, in particular for micro and submicrometer patterns obtained via nanoimprint lithography. The patterns reveal low specific resistivity (ρ ≈ 10^–7 Ω m) and good transmittance (> 50 %) in the visible range enabling applications in optoelectronic devices.