Synthesis and film formation of furfuryl- and maleimido carbonic acid derivatives of dextran

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Thomas Elschner - , University of Maribor, Friedrich-Schiller-Universität Jena (Autor:in)
  • Franziska Obst - , Friedrich-Schiller-Universität Jena (Autor:in)
  • Karin Stana-Kleinschek - , European Polysaccharide Network of Excellence (EPNOE) (Autor:in)
  • Rupert Kargl - , University of Maribor (Autor:in)
  • Thomas Heinze - , Friedrich-Schiller-Universität Jena, European Polysaccharide Network of Excellence (EPNOE) (Autor:in)

Abstract

Carbonic acid derivatives of dextran possessing furfuryl-and maleimido moieties were synthesized and processed into thin films by spin coating. First, products with different degrees of substitution (DS) of up to 3.0 and substitution patterns were obtained and characterized by NMR-and FTIR spectroscopy, as well as elemental analysis. Thin films possessing maleimide groups were obtained by spin coating of maleimido dextran (furan-protected) and dextran furfuryl carbamate that was converted with bismaleimide. The removal of the protecting group (furan) on the thin film was monitored by QCM-D and compared with gravimetric analysis of the bulk material. Film morphology and wettability were determined by means of AFM and contact angle measurements. (C) 2016 Elsevier Ltd. All rights reserved.

Details

OriginalspracheEnglisch
Seiten (von - bis)1-9
Seitenumfang9
FachzeitschriftCarbohydrate polymers
Jahrgang161
PublikationsstatusVeröffentlicht - 1 Apr. 2017
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

Scopus 85008195169

Schlagworte

Schlagwörter

  • Dextran, Synthesis, Furfuryl carbamate, Maleimido carbonate, Thin film, NANOPARTICLES, PEPTIDE, DESIGN, ESTERS