Synergistic effect between electroactive tetraphenyl-P -phenylenediamine and AIE-active tetraphenylethylene for highly integrated electrochromic/electrofluorochromic performances

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Ningwei Sun - , Professur für Organische Bauelemente (cfaed), Jilin University, Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • Kaixin Su - , Jilin University (Autor:in)
  • Ziwei Zhou - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • Xuzhou Tian - , Jilin University (Autor:in)
  • Daming Wang - , Jilin University (Autor:in)
  • Nicole Vilbrandt - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • Andreas Fery - , Professur für Physikalische Chemie polymerer Materialien (gB/IPF) (PC5), Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • Franziska Lissel - , Leibniz-Institut für Polymerforschung Dresden (Autor:in)
  • Xiaogang Zhao - , Jilin University (Autor:in)
  • Chunhai Chen - , Jilin University (Autor:in)

Abstract

Switchable fluorescent materials have gained great attention due to their promising applications in sensors, memory devices and displays. However, further progress is hindered by the low fluorescence contrast, modest response speed and inferior long-term cycling stability. Based on a rational design strategy by combining a highly conjugated tetraphenyl-p-phenylenediamine (TPPA) unit and an aggregation induced emission (AIE)-active tetraphenylethylene (TPE) unit, we synthesized a novel diamine "N,N′-bis(4-aminophenyl)-N,N′-di(4-(1,2,2-triphenylethenyl)phenyl)-1,4-phenylenediamine" to construct an electro- and AIE-active polymer. In addition to the high efficiency solid-state fluorescence and the extremely stable redox properties, the resulting polymer TPE-TPPA-PA realized highly integrated emission/color dual-switchable properties, including multistage color-changing, high fluorescence on/off contrast up to 252, impressively rapid response rate (1.3/0.5 s for EC and 0.7/2.1 s for EFC processes) and excellent cycling stability over 10000 s. The demonstrated synergistic effect between stable electroactive TPPA and AIE-active TPE may provide a new pathway for further molecular design to realize high-performance emission/color dual-switchable materials.

Details

OriginalspracheEnglisch
Seiten (von - bis)9308-9315
Seitenumfang8
FachzeitschriftJournal of Materials Chemistry C
Jahrgang7
Ausgabenummer30
PublikationsstatusVeröffentlicht - 2019
Peer-Review-StatusJa

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