Structural anisotropy in three dimensional macroporous graphene: A polarized XANES investigation

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • S. J. Rezvani - , National Institute for Nuclear Physics (Autor:in)
  • A. D'Elia - , National Institute for Nuclear Physics, Università degli Studi di Trieste (Autor:in)
  • S. Macis - , National Institute for Nuclear Physics, University of Rome La Sapienza (Autor:in)
  • S. Nannarone - , National Institute for Nuclear Physics (Autor:in)
  • S. Lupi - , National Institute for Nuclear Physics, University of Rome La Sapienza (Autor:in)
  • F. Schütt - , Christian-Albrechts-Universität zu Kiel (CAU) (Autor:in)
  • F. Rasch - , Christian-Albrechts-Universität zu Kiel (CAU) (Autor:in)
  • R. Adelung - , Christian-Albrechts-Universität zu Kiel (CAU) (Autor:in)
  • B. Lu - , Beijing Institute of Technology (Autor:in)
  • Z. Zhang - , Beijing Institute of Technology (Autor:in)
  • L. Qu - , Beijing Institute of Technology (Autor:in)
  • X. Feng - , Professur für Molekulare Funktionsmaterialien (cfaed) (Autor:in)
  • A. Romani Vázquez - , Professur für Molekulare Funktionsmaterialien (cfaed) (Autor:in)
  • A. Marcelli - , National Institute for Nuclear Physics, Rome International Center for Materials Science, Sincrotrone Trieste (Autor:in)

Abstract

Three-dimensional macroporous graphene sponges with different densities were investigated by angular dependent carbon K-edge X-ray Absorption Near Edge Spectroscopy (XANES) with a linearly polarized beam. The C K-edge XANES analysis shows an unexpected anisotropic behavior of the macroporous graphene random networks. The macroporous graphene sponges expectedly show an exceedingly lower dichroic ratio compared with that of the highly oriented pyrolytic graphite, but spectra clearly points out the occurrence of oriented hexagonal carbon planes. The anisotropy of the investigated samples exhibits a linear dependence with the measured density. The XANES analysis supports the presence of graphene-like, two-dimensional planar structures inside these synthetic sponges and correlates it with different structural networks and/or density in graphene sponges.

Details

OriginalspracheEnglisch
Aufsatznummer108171
FachzeitschriftDiamond and related materials
Jahrgang111
PublikationsstatusVeröffentlicht - Jan. 2021
Peer-Review-StatusJa

Schlagworte

Schlagwörter

  • Dichroism, Graphene, Macroporous, Sponges, X-ray absorption spectroscopy

Bibliotheksschlagworte