Semitransparent Perovskite Solar Cells with an Evaporated Ultra-Thin Perovskite Absorber
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Metal halide perovskites are of great interest for application in semitransparent solar cells due to their tunable bandgap and high performance. However, fabricating high-efficiency perovskite semitransparent devices with high average visible transmittance (AVT) is challenging because of their high absorption coefficient. Here, a co-evaporation process is adopted to fabricate ultra-thin CsPbI3 perovskite films. The smooth surface and orientated crystal growth of the evaporated perovskite films make it possible to achieve 10 nm thin films with compact and continuous morphology without pinholes. When integrated into a p-i-n device structure of glass/ITO/PTAA/perovskite/PCBM/BCP/Al/Ag with an optimized transparent electrode, these ultra-thin layers result in an impressive open-circuit voltage (VOC) of 1.08 V and a fill factor (FF) of 80%. Consequently, a power conversion efficiency (PCE) of 3.6% with an AVT above 50% is demonstrated, which is the first report for a perovskite device of a 10 nm active layer thickness with high VOC, FF and AVT. These findings demonstrate that deposition by thermal evaporation makes it possible to form compact ultra-thin perovskite films, which are of great interest for future smart windows, light-emitting diodes, and tandem device applications.
Details
| Originalsprache | Englisch |
|---|---|
| Aufsatznummer | 2307471 |
| Seitenumfang | 11 |
| Fachzeitschrift | Advanced functional materials |
| Jahrgang | 34 |
| Ausgabenummer | 50 |
| Frühes Online-Datum | 29 Juni 2023 |
| Publikationsstatus | Veröffentlicht - 9 Dez. 2024 |
| Peer-Review-Status | Ja |
Schlagworte
ASJC Scopus Sachgebiete
- Elektronische, optische und magnetische Materialien - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
- Allgemeine Chemie - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
- Biomaterialien - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
- Allgemeine Materialwissenschaften - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
- Physik der kondensierten Materie - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
- Elektrochemie - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
Schlagwörter
- co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
Bibliotheksschlagworte
- 620 Ingenieurwissenschaften und zugeordnete Tätigkeiten - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
- 540 Chemie und zugeordnete Wissenschaften - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites
- 530 Physik - co-evaporation process, CsPbI, semitransparent perovskite solar cells, transparent electrodes, ultra-thin perovskites