Lithium-sulfur (Li–S) batteries are among the targeted candidates for future generation secondary batteries with high specific energy. Herein, a scalable synthesis is presented to produce highly porous, nitrogen-doped carbons from a commercial carbon black material by melamine impregnation and subsequent thermolysis. The process up-scaling up was demonstrated at > 100 g batch level. The nitrogen doping was controlled through pyrolysis temperatures and carbon to melamine ratio. The sulfur-carbon cathodes exhibit an enhanced cycle life at a moderate electrolyte to sulfur ratio of 7 μL mg_S ⁻¹. In particular, under lean conditions at low electrolyte amount of 5 μL mg_S ⁻¹, the nitrogen functionalities improved active material utilization and capacity retention significantly. The nitrogen-doped scaffold was integrated into five-layered prototype cell (71 × 46 mm²) with a capacity of up to 0.87 Ah reaching a specific energy density of 238 Wh kg⁻¹ on stack level. These results provide new insights into realistic application of nitrogen-doped carbons on pouch cell level.