Preparation and characterization of a ligand-stabilized trimethylphosphane dication

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

Abstract

The ditriflate salt of the DMAP-stabilized trimethylphosphane dication is formed from the reaction of chlorotrimethylphosphonium triflate with DMAP (4-dimethylaminopyridine) in the presence of trimethylsilyltriflate and also from the reaction of DMAP-dimethylphosphenium triflate with methyltriflate. The coordinative nature of the DMAP–phosphorus bond is demonstrated by a ligand exchange of DMAP for PMe3 to give the hexamethyldiphosphonium dication. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

Details

OriginalspracheEnglisch
FachzeitschriftEuropean journal of inorganic chemistry
Jahrgang2007
Ausgabenummer31
PublikationsstatusVeröffentlicht - 2007
Peer-Review-StatusJa

Externe IDs

WOS 000250940500002
Scopus 36048945418

Schlagworte

Bibliotheksschlagworte