Organic tandem solar cells: How impedance analyses can improve the quality of external quantum efficiency measurements

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Daniel Bahro - , Karlsruher Institut für Technologie (Autor:in)
  • Manfred Wilck - , Karlsruher Institut für Technologie (Autor:in)
  • Adrian Mertens - , Karlsruher Institut für Technologie (Autor:in)
  • Bernd Ebenhoch - , Karlsruher Institut für Technologie (Autor:in)
  • Elizabeth von Hauff - , Vrije Universiteit Amsterdam (VU) (Autor:in)
  • Alexander Colsmann - , Karlsruher Institut für Technologie (Autor:in)

Abstract

Tandem architectures are one of the most promising concepts towards superior power conversion efficiencies of organic solar cells. An accurate determination of the power conversion efficiency requires correction of the spectral mismatch and thus relies on accurate external quantum efficiency (EQE) spectra. Due to the series connection of 2 subcells in the tandem architecture, the EQE of the tandem solar cell reproduces the EQE of one subcell if an appropriate bias light is chosen to selectively illuminate and hence forward bias the other subcell. The resulting internal voltage drop is then compensated by applying an external voltage to the tandem solar cell. In this work, we use impedance spectroscopy to accurately predict the minimum bias light intensity and the external voltage to enable accurate EQE measurements on both subcells. We exemplify this procedure on organic tandem solar cells comprising spectrally complementary absorbers and suggest an extended protocol for future measurements of the EQE.

Details

OriginalspracheEnglisch
Seiten (von - bis)763-777
Seitenumfang15
FachzeitschriftProgress in Photovoltaics: Research and Applications
Jahrgang26
Ausgabenummer10
PublikationsstatusVeröffentlicht - Okt. 2018
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

ORCID /0000-0002-6269-0540/work/172082523

Schlagworte

Ziele für nachhaltige Entwicklung

Schlagwörter

  • bias illumination, bias voltage, EQE, impedance spectroscopy, organic photovoltaics, tandem solar cell

Bibliotheksschlagworte