Two novel cyclodiphosphazane cluster frameworks with Cu₄X₄ clusters as tetrahedral nodes and ferrocenyl cyclodiphosphazanes [Fe(η⁵-C₅H₄)₂(PN^tBu)₂] as ditopic linkers have been synthesized. These frameworks having sodalite topology display a unique integration of porosity and redox activity and offer new opportunities for the synthesis of zeotype frameworks with soft phosphorus-based ligands.