Nonequilibrium sorption of phenols onto geosorbents: The impact of pH on intraparticle mass transfer
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
While the pH effect on sorption equilibrium of weak acids on natural sorbents was investigated in a number of studies, less is known about the pH dependence of sorption kinetics. This paper investigates the impact of pH on sorption kinetics during the transport of some selected phenols through a sandy aquifer material. Breakthrough curves measured in column experiments were analyzed using a mass transfer based nonequilibrium model designated as dispersed flow, film and particle diffusion model (DF-FPDM). In this model, the rate limiting intraparticle diffusion is characterized by the mass transfer coefficient, kSaV, which can be determined from breakthrough curves by curve fitting. The experimental results indicate that the kSaV is pH-dependent and inversely correlated with the pH-dependent distribution coefficient, Kd,app. Regression equations are presented that may be used to estimate approximate values of intraparticle mass transfer coefficients on the basis of experimentally determined or LFER predicted distribution coefficients.
Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 1419-1426 |
| Seitenumfang | 8 |
| Fachzeitschrift | Chemosphere |
| Jahrgang | 61 |
| Ausgabenummer | 10 |
| Publikationsstatus | Veröffentlicht - Dez. 2005 |
| Peer-Review-Status | Ja |
Externe IDs
| Scopus | 27944480026 |
|---|---|
| PubMed | 15982712 |
Schlagworte
Ziele für nachhaltige Entwicklung
- SDG 3 – Gute Gesundheit und Wohlergehen - Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols
ASJC Scopus Sachgebiete
- Environmental engineering - Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols
- Umweltchemie - Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols
- Allgemeine Chemie - Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols
- Umweltverschmutzung - Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols
- Öffentliche Gesundheit, Umwelt- und Arbeitsmedizin - Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols
- Gesundheit, Toxikologie und Mutagenese - Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols
Schlagwörter
- Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols