Nonequilibrium sorption of phenols onto geosorbents: The impact of pH on intraparticle mass transfer

Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung

Beitragende

Abstract

While the pH effect on sorption equilibrium of weak acids on natural sorbents was investigated in a number of studies, less is known about the pH dependence of sorption kinetics. This paper investigates the impact of pH on sorption kinetics during the transport of some selected phenols through a sandy aquifer material. Breakthrough curves measured in column experiments were analyzed using a mass transfer based nonequilibrium model designated as dispersed flow, film and particle diffusion model (DF-FPDM). In this model, the rate limiting intraparticle diffusion is characterized by the mass transfer coefficient, kSaV, which can be determined from breakthrough curves by curve fitting. The experimental results indicate that the kSaV is pH-dependent and inversely correlated with the pH-dependent distribution coefficient, Kd,app. Regression equations are presented that may be used to estimate approximate values of intraparticle mass transfer coefficients on the basis of experimentally determined or LFER predicted distribution coefficients.

Details

OriginalspracheEnglisch
Seiten (von - bis)1419-1426
Seitenumfang8
FachzeitschriftChemosphere
Jahrgang61
Ausgabenummer10
PublikationsstatusVeröffentlicht - Dez. 2005
Peer-Review-StatusJa

Externe IDs

Scopus 27944480026
PubMed 15982712

Schlagworte

Ziele für nachhaltige Entwicklung

ASJC Scopus Sachgebiete

Schlagwörter

  • Geosorbents, Intraparticle mass transfer, LFER, Nonequilibrium sorption, pH-dependent sorption, Phenols