NMR-investigation of restricted self-diffusion of oil in rape seeds

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • G. Fleischer - , Universität Leipzig (Autor:in)
  • V. D. Skirda - , Kazan Volga Region Federal University (Autor:in)
  • A. Werner - , Ingenieurhochschule Berlin-Wartenberg (Autor:in)

Abstract

The self-diffusion of oil and water in rape seeds (Brassica napus L.) was measured with the NMR pulsed field gradient technique. The self-diffusion of oil was found to be completely restricted for diffusion times Δ > 30 ms. The experiments could be explained in terms of the model of diffusion within spherical droplets and a Gaussian mass distribution of the droplet radii. The mean droplet radius was found to be about 0.7 μm; this value decreased somewhat with increasing moisture content of the seeds. The experiments could also be explained with a Gaussian number distribution of droplet radii and a fraction of immobile protons in the NMR signal of 5 ... 10%, possibly arising from lipid protons. Though the transverse nuclear magnetic relaxation decay of the oil protons is not a single exponential we observe one uniform diffusive mobility for the oil molecules. The water self-diffusion coefficient at maximum moisture content of about 40% was determined to be 4.2 · 10-10 m2 s-1 which is typical for swollen polymer-solvent systems at such a concentration.

Details

OriginalspracheEnglisch
Seiten (von - bis)25-30
Seitenumfang6
FachzeitschriftEuropean biophysics journal : with biophysics letters
Jahrgang19
Ausgabenummer1
PublikationsstatusVeröffentlicht - Sept. 1990
Peer-Review-StatusJa
Extern publiziertJa

Externe IDs

ORCID /0000-0001-8204-5699/work/154738459

Schlagworte

ASJC Scopus Sachgebiete

Schlagwörter

  • NMR pulsed field gradient technique, Oil, Rape seeds, Self-diffusion