Magnetically confined surface and bulk excitons in a layered antiferromagnet

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Yinming Shao - , Columbia University, Pennsylvania State University (Autor:in)
  • Florian Dirnberger - , Professur für Ultraschnelle Mikroskopie und Photonik (ct.qmat), Technische Universität Dresden, Technische Universität München, Munich Center for Quantum Science and Technology (MCQST) (Autor:in)
  • Siyuan Qiu - , Columbia University (Autor:in)
  • Swagata Acharya - , National Renewable Energy Laboratory (Autor:in)
  • Sophia Terres - , Institut für Angewandte Physik (IAP), Professur für Ultraschnelle Mikroskopie und Photonik (ct.qmat) (Autor:in)
  • Evan J. Telford - , Columbia University (Autor:in)
  • Dimitar Pashov - , King's College London (KCL) (Autor:in)
  • Brian S.Y. Kim - , Columbia University, University of Arizona (Autor:in)
  • Francesco L. Ruta - , Columbia University (Autor:in)
  • Daniel G. Chica - , Columbia University (Autor:in)
  • Avalon H. Dismukes - , Columbia University (Autor:in)
  • Michael E. Ziebel - , Columbia University (Autor:in)
  • Yiping Wang - , Columbia University (Autor:in)
  • Jeongheon Choe - , Columbia University (Autor:in)
  • Youn Jue Bae - , Columbia University (Autor:in)
  • Andrew J. Millis - , Columbia University, Simons Foundation (Autor:in)
  • Mikhail I. Katsnelson - , Radboud University Nijmegen (Autor:in)
  • Kseniia Mosina - , University of Chemistry and Technology, Prague (Autor:in)
  • Zdenek Sofer - , University of Chemistry and Technology, Prague (Autor:in)
  • Rupert Huber - , Universität Regensburg (Autor:in)
  • Xiaoyang Zhu - , Columbia University (Autor:in)
  • Xavier Roy - , Columbia University (Autor:in)
  • Mark van Schilfgaarde - , National Renewable Energy Laboratory (Autor:in)
  • Alexey Chernikov - , Professur für Ultraschnelle Mikroskopie und Photonik (ct.qmat), Exzellenzcluster ct.qmat: Komplexität und Topologie in Quantenmaterialien (Autor:in)
  • D. N. Basov - , Columbia University (Autor:in)

Abstract

The discovery of two-dimensional van der Waals magnets has greatly expanded our ability to create and control nanoscale quantum phases. A unique capability emerges when a two-dimensional magnet is also a semiconductor that features tightly bound excitons with large oscillator strengths that fundamentally determine the optical response and are tunable with magnetic fields. Here we report a previously unidentified type of optical excitation—a magnetic surface exciton—enabled by the antiferromagnetic spin correlations that confine excitons to the surface of CrSBr. Magnetic surface excitons exhibit stronger Coulomb attraction, leading to a higher binding energy than excitons confined in bulk layers, and profoundly alter the optical response of few-layer crystals. Distinct magnetic confinement of surface and bulk excitons is established by layer- and temperature-dependent exciton reflection spectroscopy and corroborated by ab initio many-body perturbation theory calculations. By quenching interlayer excitonic interactions, the antiferromagnetic order of CrSBr strictly confines the bound electron–hole pairs within the same layer, regardless of the total number of layers. Our work unveils unique confined excitons in a layered antiferromagnet, highlighting magnetic interactions as a vital approach for nanoscale quantum confinement, from few layers to the bulk limit.

Details

OriginalspracheEnglisch
Aufsatznummereaav4450
Seiten (von - bis)391-398
Seitenumfang8
FachzeitschriftNature materials
Jahrgang24
Ausgabenummer3
PublikationsstatusVeröffentlicht - März 2025
Peer-Review-StatusJa

Externe IDs

ORCID /0000-0002-9213-2777/work/196666295