Laser- and collision-induced nonadiabatic wave-packet dynamics in sodium molecules
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
- Technische Universität Dresden
- Stockholm University
Abstract
We investigate nonadiabatic dynamics of molecular sodium in two alternative approximate ways. Firstly, the semiclassical mapping formalism is used to study the decisive step in resonant two photon ionization of Nan, where the Rabi oscillations of the occupation probability of the resonantly excited intermediate state are reproduced with a high degree of accuracy. Secondly, nonadiabatic quantum molecular dynamics is combined with the surface hopping approach of Tully in order to take into account quantum effects on the nuclear dynamics in collisionally excited sodium molecular ions. Their importance is demonstrated by comparing the results with experimental fragment correlations of kinematically complete experiments.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 785-793 |
Seitenumfang | 9 |
Fachzeitschrift | Annalen der Physik |
Jahrgang | 9 |
Ausgabenummer | 9-10 |
Publikationsstatus | Veröffentlicht - 2000 |
Peer-Review-Status | Ja |
Externe IDs
Scopus | 0033695863 |
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Schlagworte
Schlagwörter
- nonadiabatic dynamics, semiclassical wave-packet propagation, molecular dynamics, INDUCED DISSOCIATION, EXCITED-STATES, IONIZATION, H-2(+), PULSES, FIELD, IONS, TIME, NA2