Insights into different photoluminescence mechanisms of binary and ternary aqueous nanocrystals from the temperature dependence: A case study of CdSe and Ag-In-S
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
A comparative study of the temperature dependences of the photoluminescence (PL) of aqueous CdSe and silver-indium-sulfide (AIS) nanocrystals (NCs) in a broad range of 10-310 K is reported. Gelatin-incorporated CdSe (and core/shell CdSe/ZnS) NCs reveal both direct (excitonic) and trap-state-mediated PL components with different temperature dependences of the PL band maximum and spectral width. Glutathione-capped AIS (and core/shell AIS/ZnS) NCs emit a single broad PL band resembling the trap-related PL of CdSe NCs but showing nevertheless a temperature PL dependence typical for excitonic PL. In combination with previously reported results, these special features allow the PL emission of ternary AIS (AIS/ZnS) NCs to be explained based on the recombination of self-trapped excitons.
Details
Originalsprache | Englisch |
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Aufsatznummer | 116630 |
Seitenumfang | 8 |
Fachzeitschrift | Journal of luminescence |
Jahrgang | 215 |
Publikationsstatus | Veröffentlicht - Nov. 2019 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |
Externe IDs
Scopus | 85069741306 |
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ORCID | /0000-0002-8827-2881/work/142232977 |
Schlagworte
Schlagwörter
- Cadmium selenide, Silver indium sulfide, Quantum dots, Self-trapped exciton, SELF-TRAPPED EXCITONS, WHITE-LIGHT EMISSION, QUANTUM DOTS, SEMICONDUCTOR NANOCRYSTALS, LUMINESCENCE, NANOPARTICLES, ENERGY, SURFACE, FLUORESCENCE