Calcium aluminate electride (named as C12A7) has become an active topic as a material for electron emission in the research field of electron sources, especially for electric propulsion, in recent years. Whereas the initially predicted, extremely low work function of 0.6 eV could not be confirmed experimentally at technically relevant surface current densities, the material remains an attractive emitter. Besides C12A7 emitting electrons at lower temperatures compared to LaB₆, it appears to be resistant to poisoning and even iodine compatible as only known low work function material. On the other hand, the ceramic electride nature of the emitter introduces challenges related to the thermal, mechanical and electrical properties. Therefore, C12A7 has been investigated experimentally as a candidate material for thermionic emitters in space applications. The aim of this study was to enhance the thermionic emission by material modifications such as surface treatments, electrical contacting methods and doping of the C12A7. The performance improvement was quantified in a thermionic diode configuration, in which the emission current was determined as a function of temperature over multiple heating cycles to observe time dependent effects. The surface treatment such as grinding or polishing affects the emission properties of the C12A7 negatively. In contrary, the doping of the C12A7 lattice as well as the contacting of the back side (heater side) significantly improved the emission as well as the measured current density.