Impact of Particle Morphology on Processing and Performance of Sodium Ion Anodes

Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung

Beitragende

  • Johannes Kühn - , Professur für Anorganische Chemie (I) (AC1), Fraunhofer-Institut für Werkstoff- und Strahltechnik (Autor:in)
  • Tom Boenke - , Fraunhofer-Institut für Werkstoff- und Strahltechnik (Autor:in)
  • Florian S. Hoffmann - , Fraunhofer-Institut für Werkstoff- und Strahltechnik (Autor:in)
  • Thomas Abendroth - , Fraunhofer-Institut für Werkstoff- und Strahltechnik (Autor:in)
  • Holger Althues - , Fraunhofer-Institut für Werkstoff- und Strahltechnik (Autor:in)
  • Stefan Kaskel - , Professur für Anorganische Chemie (I) (AC1), Fraunhofer-Institut für Werkstoff- und Strahltechnik (Autor:in)

Abstract

Despite pronounced research on hard carbon (HC) anode materials for sodium-ion batteries (SIB), particularly the impact of particle morphology on electrode microstructure poses open questions regarding ionic as well as electrical transport or sodium metal plating. This study systematically compares two hard carbons, one representing a nonspherical particle morphology (HC-Ref) and the other representing a spherical particle morphology (HC-Sph-10:90). Industrially relevant loadings were investigated across powder, electrode, half-cell, and full-cell configurations. The analysis of powder and electrode microstructure revealed that spherical particles exhibited superior packing efficiency, leading to higher electrode densities, whereas nonspherical particles retained electrode porosity upon calendaring, thereby enhancing ionic transport. The formation of multipoint contacts was identified to enhance conductive pathways. The electrochemical characterization revealed a clear trade-off between the dense packing and transport capability of the anode. This trade-off translated into three-electrode full cells, where morphology-related polarization affected the potential-defined onset of sodium metal plating. Sodium metal plating is therefore governed by operating conditions like current density and voltage window, while the electrode structure determines the underlying transport limitations and thus the plating susceptibility. Consequently, electrode microstructure is presented as a critical design parameter, together with design guidelines for the optimization of hard carbon anodes for high-energy and plating-resistant SIBs.

Details

OriginalspracheEnglisch
Aufsatznummere70476
FachzeitschriftBatteries and Supercaps
Jahrgang9
Ausgabenummer9
PublikationsstatusVeröffentlicht - Sept. 2026
Peer-Review-StatusJa

Schlagworte

ASJC Scopus Sachgebiete

  • Energieanlagenbau und Kraftwerkstechnik - anode microstructure, anode plating, batteries, calendering, full-cell, hard carbon anode, porosity, sodium
  • Elektrotechnik und Elektronik - anode microstructure, anode plating, batteries, calendering, full-cell, hard carbon anode, porosity, sodium
  • Elektrochemie - anode microstructure, anode plating, batteries, calendering, full-cell, hard carbon anode, porosity, sodium

Schlagwörter

  • anode microstructure, anode plating, batteries, calendering, full-cell, hard carbon anode, porosity, sodium