Hydroflux syntheses and crystal structures of hydrogarnets Ba3[RE(OH)6]2(RE = Sc, Y, Ho-Lu)

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Abstract

Colorless crystals of the barium rare earth hydrogarnets Ba3[RE(OH)6]2 (RE = Sc, Y, Ho-Lu) were synthesized under hydroflux conditions with KOH at about T = 200 °C starting from the respective RE 2O3 and Ba (NO3)2. Single-crystal X-ray diffraction analysis on these distorted rhombic dodecahedra revealed the cubic space group Ia 3 - $ {3}$ d (no. 230). The crystal structures of the hydrogarnets Ba3[RE(OH)6]2 are discussed and compared with those of other hydrogarnets. The occurrence of additional reflections, which do not fulfill the reflection conditions of Ia 3 -e;{3}$ d, is analyzed and described by Renninger or λ/2 effects. A correlation is established between the space group adopted by a hydrogarnet and characteristic interatomic distances. In addition, single-crystal structure data of the strontium indium hydrogarnet Sr3[In(OH)6]2 are provided.

Details

OriginalspracheEnglisch
Seiten (von - bis)951-957
Seitenumfang7
FachzeitschriftZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Jahrgang75
Ausgabenummer11
PublikationsstatusVeröffentlicht - 2020
Peer-Review-StatusJa

Externe IDs

Scopus 85096485545
ORCID /0000-0001-7523-9313/work/142238568
ORCID /0000-0002-2391-6025/work/142250187

Schlagworte