High-power lithium ion batteries based on preorganized necklace type Li4Ti5O12/VACNT nano-composites
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
Li4Ti5O12 as anode material for high power Li+-ion batteries is very promising due to its unique electronic properties. However, the lack of electronic conductivity as well as the low Li+-ion diffusion coefficient are major drawbacks in achieving high power densities. In this work, therefore, we prepared a nano-composite consisting of vertically aligned carbon nanotube arrays decorated with in-situ grown necklace type Li4Ti5O12 nanoparticles. Owing to this structure the electrodes exhibit outstanding rate performances with specific capacities of 110 mAh g-1 up to 300C and cycling performance with high capacity retention of 97% after 500 cycles at 10C. Thus, the combination of short Li+-ion diffusion distances within Li4Ti5O12 particles, remarkable electronic conductivity by carbon nanotubes directly grown on the current collector as well as a high contact surface area due to an open pore geometry is essential in achieving high power Li4Ti5O12 anodes.
Details
Originalsprache | Englisch |
---|---|
Seiten (von - bis) | 1-6 |
Seitenumfang | 6 |
Fachzeitschrift | Journal of power sources |
Jahrgang | 325 |
Publikationsstatus | Veröffentlicht - 1 Sept. 2016 |
Peer-Review-Status | Ja |
Schlagworte
Ziele für nachhaltige Entwicklung
ASJC Scopus Sachgebiete
Schlagwörter
- High-power lithium ion batteries, LiTiO (LTO), Nano-composite, Nanotube array, Vertically aligned carbon nanotubes (VACNT)