High-power lithium ion batteries based on preorganized necklace type Li4Ti5O12/VACNT nano-composites

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Fabian Pawlitzek - , Professur für Anorganische Chemie (I) (AC1), Fraunhofer Institute for Material and Beam Technology (Autor:in)
  • Jonas Pampel - , Fraunhofer Institute for Material and Beam Technology, Max Planck Institute of Colloids and Interfaces (Autor:in)
  • Martin Schmuck - , VARTA Micro Innovation GmbH (Autor:in)
  • Holger Althues - , Fraunhofer Institute for Material and Beam Technology (Autor:in)
  • Benjamin Schumm - , Fraunhofer Institute for Material and Beam Technology (Autor:in)
  • Stefan Kaskel - , Professur für Anorganische Chemie (I) (AC1), Fraunhofer Institute for Material and Beam Technology (Autor:in)

Abstract

Li4Ti5O12 as anode material for high power Li+-ion batteries is very promising due to its unique electronic properties. However, the lack of electronic conductivity as well as the low Li+-ion diffusion coefficient are major drawbacks in achieving high power densities. In this work, therefore, we prepared a nano-composite consisting of vertically aligned carbon nanotube arrays decorated with in-situ grown necklace type Li4Ti5O12 nanoparticles. Owing to this structure the electrodes exhibit outstanding rate performances with specific capacities of 110 mAh g-1 up to 300C and cycling performance with high capacity retention of 97% after 500 cycles at 10C. Thus, the combination of short Li+-ion diffusion distances within Li4Ti5O12 particles, remarkable electronic conductivity by carbon nanotubes directly grown on the current collector as well as a high contact surface area due to an open pore geometry is essential in achieving high power Li4Ti5O12 anodes.

Details

OriginalspracheEnglisch
Seiten (von - bis)1-6
Seitenumfang6
FachzeitschriftJournal of power sources
Jahrgang325
PublikationsstatusVeröffentlicht - 1 Sept. 2016
Peer-Review-StatusJa

Schlagworte

Ziele für nachhaltige Entwicklung

Schlagwörter

  • High-power lithium ion batteries, LiTiO (LTO), Nano-composite, Nanotube array, Vertically aligned carbon nanotubes (VACNT)