GeP3: A Small Indirect Band Gap 2D Crystal with High Carrier Mobility and Strong Interlayer Quantum Confinement
Publikation: Beitrag in Fachzeitschrift › Forschungsartikel › Beigetragen › Begutachtung
Beitragende
Abstract
We propose a two-dimensional crystal that possesses low indirect band gaps of 0.55 eV (monolayer) and 0.43 eV (bilayer) and high carrier mobilities similar to those of phosphorene, GeP3. GeP3 has a stable three-dimensional layered bulk counterpart, which is metallic and known from experiment since 1970. GeP3 monolayer has a calculated cleavage energy of 1.14 J m-2, which suggests exfoliation of bulk material as viable means for the preparation of mono- and few-layer materials. The material shows strong interlayer quantum confinement effects, resulting in a band gap reduction from mono- to bilayer, and then to a semiconductor-metal transition between bi- and triple layer. Under biaxial strain, the indirect band gap can be turned into a direct one. Pronounced light absorption in the spectral range from ∼600 to 1400 nm is predicted for monolayer and bilayer and promises applications in photovoltaics.
Details
Originalsprache | Englisch |
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Seiten (von - bis) | 1833-1838 |
Seitenumfang | 6 |
Fachzeitschrift | Nano letters |
Jahrgang | 17 |
Ausgabenummer | 3 |
Publikationsstatus | Veröffentlicht - 8 März 2017 |
Peer-Review-Status | Ja |
Extern publiziert | Ja |
Externe IDs
PubMed | 28125237 |
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Schlagworte
ASJC Scopus Sachgebiete
Schlagwörter
- 2D crystals, black phosphorus, blue phosphorus, density functional theory, electronic properties, germanium phosphide, low band gap, phosphorene