Effect of Precursor Stoichiometry on the Performance and Stability of MAPbBr3 Photovoltaic Devices

Publikation: Beitrag in FachzeitschriftForschungsartikelBeigetragenBegutachtung

Beitragende

  • Lukas M. Falk - , Universität Heidelberg (Autor:in)
  • Katelyn P. Goetz - , Universität Heidelberg (Autor:in)
  • Vincent Lami - , Universität Heidelberg (Autor:in)
  • Qingzhi An - , Universität Heidelberg (Autor:in)
  • Paul Fassl - , Universität Heidelberg (Autor:in)
  • Jonas Herkel - , Universität Heidelberg (Autor:in)
  • Fabian Thome - , Universität Heidelberg (Autor:in)
  • Alexander D. Taylor - , Universität Heidelberg (Autor:in)
  • Fabian Paulus - , Universität Heidelberg (Autor:in)
  • Yana Vaynzof - , Universität Heidelberg (Autor:in)

Abstract

The wide-bandgap methylammonium lead bromide perovskite is promising for applications in tandem solar cells and light-emitting diodes. Despite its utility, there is a limited understanding of its reproducibility and stability. Herein, the dependence of the properties, performance, and shelf storage of thin films and devices on minute changes to the precursor solution stoichiometry is examined in detail. Although photovoltaic cells based on these solution changes exhibit similar initial performance, shelf storage depends strongly on precursor solution stoichiometry. While all devices exhibit some degree of healing, bromide-deficient films show a remarkable improvement, more than doubling in their photoconversion efficiency. Photoluminescence spectroscopy experiments performed under different atmospheres suggest that this increase is due, in part, to a trap-healing mechanism that occurs upon exposure to the environment. The results highlight the importance of understanding and manipulating defects in lead halide perovskites to produce long-lasting, stable devices.

Details

OriginalspracheEnglisch
Aufsatznummer1900737
FachzeitschriftEnergy technology
Jahrgang8
Ausgabenummer4
PublikationsstatusVeröffentlicht - 1 Apr. 2020
Peer-Review-StatusJa
Extern publiziertJa

Schlagworte

Ziele für nachhaltige Entwicklung

ASJC Scopus Sachgebiete

Schlagwörter

  • lead bromide perovskites, photovoltaic devices, reproducibility, stability, stoichiometry