The invention relates to a method for the production of doped organic semiconductor materials with increased charge carrier mobility and effective charge carrier mobility by doping with a doping agent. The doping agent is produced, essentially, by electro-crystallization in a first step and is selected from a group of organic compounds having a reduced oxidation potential. An organic semiconductor material is doped with the doping agent in a second step. Furthermore, the invention also relates to doped organic semi-conductor materials with increased charge carrier mobility and effective charge carrier mobility that are produced according to the above-mentioned method. In addition, the invention further relates to an organic diode comprising the doped organic semi-conductor materials that are produced according to the above-mentioned method.